I honestly don't care what a Domme wears in session as long as whatever it is puts her in the right mood. Of course, when I am not blindfolded I do admit to loving the eye candy of a Domme in latex.
My favorite outfit is probably a mini-dress that shows and supports her breasts while falling just below the curve of her ass. Add in thigh-high boots and 3/4 length gloves (either with nails built-on or fingerless so I can feel her own fingernails marking me) to complete the ensemble.
However, I do love the look of a corset (usually not latex) over both pants or a skirt when it comes to latex. Pretty much the only thing I don't like much is a hood because it changes the way a Domme looks in such a fundamental way and makes her sort of generic rather than the person I wish to serve and please.
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Mistress, anything on you will suffice, especially the moment I see your eyes, but Medical Fetish Nurse latex has become an incredible turn on for me especially if it is worn by an evil, sadistic nurse dressed in black or red latex.